Dichlorido[3-dimethylamino-N-(2-pyridylmethylene)propylamine-κ3 N,N′,N′′]cadmium(II)
نویسندگان
چکیده
In the title mononuclear Cd(II) complex, [CdCl(2)(C(11)H(17)N(3))], the Cd(II) atom is coordinated by two Cl atoms and three N atoms from the tridentate Schiff base ligand in a distorted square-pyramidal environment. The three N atoms and one Cl atom constitute the base of the pyramid, whereas the other Cl atom occupies the apical position.
منابع مشابه
Dichlorido{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}cadmium
In the title compound, [CdCl(2)(C(11)H(17)N(3))], the Schiff base acts as an N,N',N''-tridentate ligand towards the Cd(II) ion. Two Cl atoms complete a distorted square-pyramidal geometry around the metal atom. In the crystal, a C-H⋯Cl inter-action connects pairs of mol-ecules into centrosymetric dimers.
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In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is five-coordinate, with the N,N',N''-tridentate Schiff base ligand 2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine and two Cl atoms in a distorted square-pyramidal geometry. In the crystal structure, C-H⋯Cl hydrogen-bonding inter-actions connect the mol-ecules into a three-dimensional network.
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متن کاملDichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3 N,N′,N′′}copper(II)
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متن کاملBis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato-κ3 N,N′,O 1}nickel(II)
The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008